diff --git a/src/plugins/intel_npu/src/plugin/npuw/llm_compiled_model.cpp b/src/plugins/intel_npu/src/plugin/npuw/llm_compiled_model.cpp
index 0232811dfb800e..853c839ff6faa1 100644
--- a/src/plugins/intel_npu/src/plugin/npuw/llm_compiled_model.cpp
+++ b/src/plugins/intel_npu/src/plugin/npuw/llm_compiled_model.cpp
@@ -448,6 +448,8 @@ ov::npuw::LLMCompiledModel::LLMCompiledModel(const std::shared_ptr<ov::Model>& m
     // preserve them somewhere.
     auto prefill_config_opt = pop_option(npuw_llm_props, std::string("NPUW_LLM_PREFILL_CONFIG"));
     auto generate_config_opt = pop_option(npuw_llm_props, std::string("NPUW_LLM_GENERATE_CONFIG"));
+    auto prefill_config_addition = pop_option(npuw_llm_props, std::string("++NPUW_LLM_PREFILL_CONFIG"));
+    auto generate_config_addition = pop_option(npuw_llm_props, std::string("++NPUW_LLM_GENERATE_CONFIG"));
 
     m_cfg.update(any_copy(npuw_llm_props));
 
@@ -501,8 +503,15 @@ ov::npuw::LLMCompiledModel::LLMCompiledModel(const std::shared_ptr<ov::Model>& m
         generate_config_opt.value_or(get_default_generate_config(kvcache_model, npudesc, generate_hint))
             .as<ov::AnyMap>();
 
+    auto prefill_config_addition_value =
+        prefill_config_addition.has_value() ? prefill_config_addition.value().as<ov::AnyMap>() : ov::AnyMap{};
+    auto generate_config_addition_value =
+        generate_config_addition.has_value() ? generate_config_addition.value().as<ov::AnyMap>() : ov::AnyMap{};
+
     merge_config_with(prefill_config, other_props);
     merge_config_with(generate_config, other_props);
+    merge_config_with(prefill_config, prefill_config_addition_value);
+    merge_config_with(generate_config, generate_config_addition_value);
 
     m_kvcache_compiled = std::dynamic_pointer_cast<ov::npuw::CompiledModel>(
         ov::npuw::ICompiledModel::create(kvcache_model, plugin, generate_config));